Question 82 marksShort AnswerSection A

An aldehyde as well as a ketone can be represented by the same molecular formula, say C3H6OC_3H_6O. Write their structures and name them. State the relation between the two in the language of science.

Also asked in:2016
Carbon and its Compounds
Chains, Branches and Rings

Official answer

For the molecular formula C3extH6extO\text{C}_3 ext{H}_6 ext{O}, the two functional group representations are:


  1. Aldehyde:
  • Name: Propanal
  • Structure:

CH3−CH2−CHO\text{CH}_3-\text{CH}_2-\text{CHO}

(Or structurally represented as:)

H−C∣HH∥−C∣HH∥−CO∥ ⁣∥−H\text{H}-\overset{\begin{matrix}\text{H}\\\|\end{matrix}}{\underset{\begin{matrix}|\\\text{H}\end{matrix}}{\text{C}}}-\overset{\begin{matrix}\text{H}\\\|\end{matrix}}{\underset{\begin{matrix}|\\\text{H}\end{matrix}}{\text{C}}}-\overset{\begin{matrix}\text{O}\\\|\!\|\end{matrix}}{\text{C}}-\text{H}


  1. Ketone:
  • Name: Propanone (commonly known as acetone)
  • Structure:

CH3−CO−CH3\text{CH}_3-\text{CO}-\text{CH}_3

(Or structurally represented as:)

H−C∣HH∥−CO∥ ⁣∥−C∣HH∥−H\text{H}-\overset{\begin{matrix}\text{H}\\\|\end{matrix}}{\underset{\begin{matrix}|\\\text{H}\end{matrix}}{\text{C}}}-\overset{\begin{matrix}\text{O}\\\|\!\|\end{matrix}}{\text{C}}-\overset{\begin{matrix}\text{H}\\\|\end{matrix}}{\underset{\begin{matrix}|\\\text{H}\end{matrix}}{\text{C}}}-\text{H}


Relation in the language of science:

These two compounds are structural isomers (specifically functional isomers). They share the same molecular formula (C3extH6extO\text{C}_3 ext{H}_6 ext{O}) but possess different functional groups (an aldehyde group −CHO-\text{CHO} in propanal, and a ketone group −CO−-\text{CO}- in propanone), which gives them distinct chemical and physical properties.

Answer keywords:PropanalPropanoneStructural isomersFunctional isomersSame molecular formula

Marking scheme

  1. 1.Correct structure and IUPAC name (Propanal) of the aldehyde. (0.5 marks)
  2. 2.Correct structure and IUPAC name (Propanone) of the ketone. (0.5 marks)
  3. 3.Identifying the relationship as 'Isomers' or 'Functional Isomers'. (0.5 marks)
  4. 4.Explaining that they have the same molecular formula but different structures/functional groups. (0.5 marks)

Hint

An aldehyde has its carbonyl group at the terminal position (−CHO-\text{CHO}), while a ketone has its carbonyl group in the middle of the carbon chain (−CO−-\text{CO}-). Compare their molecular formulas.

Quick oral answer

Propanal and propanone are functional isomers. They have the same molecular formula, C3H6O\text{C}_3\text{H}_6\text{O}, but propanal contains an aldehyde group (−CHO-\text{CHO}) while propanone contains a ketone group (−CO−-\text{CO}-).

Common mistakes

  1. 1.Naming propanone as 'propanal' or vice versa.
  2. 2.Drawing the ketone group at the terminal carbon, which incorrectly turns it into an aldehyde.
  3. 3.Forgetting to satisfy the tetravalency of carbon when drawing the structures.

Analysis and explanation

The general formula for aliphatic monohydric aldehydes and ketones is CnH2nO\text{C}_n\text{H}_{2n}\text{O}. When n=3n=3, the molecular formula is C3H6O\text{C}_3\text{H}_6\text{O}.

  • An aldehyde must have the carbonyl group (C=O\text{C}=\text{O}) at the end of the carbon chain, terminating with a hydrogen atom (−CHO-\text{CHO}). Thus, the 3-carbon chain forms propanal.
  • A ketone must have the carbonyl group (C=O\text{C}=\text{O}) bonded to two other carbon atoms internally (−CO−-\text{CO}-). Thus, the 3-carbon chain forms propanone.
  • Because they have the same molecular formula but different structural arrangements of atoms resulting in different functional groups, they are termed functional isomers.

Interesting facts

Propanone (acetone) is the simplest possible ketone because a ketone requires at least three carbon atoms to have a non-terminal carbonyl group. Propanone is widely used as a nail polish remover!

Question details

Q8 of 36 questions

Board
CBSE
Class
Class 10
Subject
Science
Year
2016
Section
Section A
Marks
2
Type
Short Answer
Chapter
Carbon and its Compounds
Topic
Chains, Branches and Rings
Also asked in
2016
Bloom's level
Understanding
Syllabus topic
Functional groups, Isomerism

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Frequently asked questions

How many marks does this question carry in CBSE Class 10 Science 2016?

This question carries 2 marks in the CBSE Class 10 Science 2016 examination.

Which chapter does this question come from in Science?

This question is from the chapter "Carbon and its Compounds" in the CBSE Class 10 Science syllabus.

What topic does this question cover in Science?

This question covers the topic "Chains, Branches and Rings" from CBSE Class 10 Science.

Has this question appeared in other CBSE Science papers?

Yes, a similar question appeared in the 2016 CBSE Class 10 Science paper.

What type of question is this in the CBSE Class 10 Science 2016 paper?

This is a Short Answer question from Section A in the CBSE Class 10 Science 2016 paper.