Q28
3 marksShort AnswerSection C

Draw a labelled diagram to show electrolytic refining of copper. State what happens when electric current is passed through the electrolyte taken in this case.

Metals and Non-metals
Refining of Metals
Official Answer

1. Labelled Diagram of Electrolytic Refining of Copper



+-Battery (DC Source)Key (Switch)Anode (+) (Impure Copper Rod)Cathode (-) (Thin Pure Copper Strip)Electrolyte (Acidified CuSO4 Solution)Anode Mud (Insoluble Impurities)Beaker


2. What Happens When Electric Current is Passed

When an electric current is passed through the acidified copper sulphate electrolyte, electrolysis takes place:


  1. At the Anode (Positive Electrode):

The impure copper atoms lose electrons and dissolve into the electrolyte solution as copper ions (Cu2+Cu^{2+}):

Cu(s)ightarrowCu2+(aq)+2eCu(s) ightarrow Cu^{2+}(aq) + 2e^{-}


  1. At the Cathode (Negative Electrode):

An equivalent amount of pure copper ions (Cu2+Cu^{2+}) from the electrolyte solution gain electrons and get deposited as pure copper metal on the cathode strip:

Cu2+(aq)+2eightarrowCu(s)Cu^{2+}(aq) + 2e^{-} ightarrow Cu(s)


  1. Impurities:
  • The soluble impurities go directly into the electrolyte solution.
  • The insoluble impurities settle down at the bottom of the beaker, directly below the anode, and are collected as anode mud.
AnodeCathodeAcidified copper sulphateAnode mudCu2+electrolysispure copper deposition

Marking Scheme

  • 11.5 marks
  • 21 mark
  • 30.5 marks

Hint

Remember: 'Anode' is positive and made of the 'impure' metal, while 'Cathode' is negative and made of the 'pure' metal. The impurities collect right under the anode.

Quick Oral Answer

Q: What is anode mud and why does it collect under the anode? A: Anode mud consists of insoluble impurities present in the impure copper anode. As the copper dissolves from the anode into the solution during electrolysis, these impurities do not dissolve and slide down to settle directly below the anode.

Analysis & Explanation

Electrolytic refining is a highly effective method used to obtain high-purity metals. In this process, the impure metal is always made the anode (connected to the positive terminal) because oxidation must occur there to dissolve the metal into the solution. The pure metal is made the cathode (connected to the negative terminal) where reduction occurs, depositing pure metal. The electrolyte is a soluble salt of the same metal (acidified copper sulphate for copper refining). This ensures a continuous transfer of pure metal ions from the anode to the cathode.

Common Mistakes

  1. 1Confusing the terminals: connecting the impure copper to the negative terminal (cathode) instead of the positive terminal (anode).
  2. 2Forgetting to label the 'anode mud' or placing it under the cathode instead of the anode.
  3. 3Not mentioning that the copper sulphate solution must be acidified to increase its electrical conductivity.

Interesting Facts

The anode mud collected during copper refining often contains precious metals like gold, silver, and platinum. Recovering these valuable metals can sometimes cover the entire cost of the electrolytic refining process!

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Frequently Asked Questions

How many marks does this question carry in CBSE Class 10 Science 2024?

This question carries 3 marks in the CBSE Class 10 Science 2024 examination.

Which chapter does this question come from in Science?

This question is from the chapter "Metals and Non-metals" in the CBSE Class 10 Science syllabus.

What topic does this question cover in Science?

This question covers the topic "Refining of Metals" from CBSE Class 10 Science.

What type of question is this in the CBSE Class 10 Science 2024 paper?

This is a Short Answer question from Section C in the CBSE Class 10 Science 2024 paper.