Question 21 markVery Short AnswerSection A

Define electropositivity.


OR


The atomic radii of first group elements are given below:


Group-I elementAtomic Radii (pm)
Na86
K231
Rb244
Cs282

State the reason behind the observed trend in the above elements.

Metals and Non-metals
Chemical Properties of Metals

Official answer

Electropositivity

Electropositivity is the tendency of an atom of an element to lose valence electrons and form positively charged ions (cations). Metals are highly electropositive because they readily lose electrons to achieve a stable octet configuration. For example, alkali metals like sodium (Na\text{Na}) and potassium (K\text{K}) react vigorously with water to form basic hydroxides by losing their valence electrons:

2Na(s)+2H2O(l)→2NaOH(aq)+H2(g)+heat energy2\text{Na(s)} + 2\text{H}_2\text{O(l)} \rightarrow 2\text{NaOH(aq)} + \text{H}_2\text{(g)} + \text{heat energy}




OR


Reason behind the observed trend in atomic radii

The atomic radius increases down the group from Sodium (Na\text{Na}) to Caesium (Cs\text{Cs}). As we move down Group 1, a new electronic shell is added at each successive step. This increases the distance between the outermost valence electrons and the nucleus. Although the nuclear charge (number of protons) also increases down the group, the effect of adding a new electronic shell far outweighs the increased nuclear attraction, resulting in an overall increase in atomic size.

Answer keywords:electropositivitylose electronscationsatomic radiusnew shellnuclear chargealkali metals

Marking scheme

  1. 1.Correct definition of electropositivity with reference to electron loss/cation formation OR correct explanation of atomic radius trend due to addition of new shells down the group.

Hint

Think about the ease with which metals lose electrons to form positive ions, or how the addition of new shells affects the distance of the outermost shell from the nucleus as you go down a group.

Quick oral answer

Electropositivity is the tendency of an element to lose electrons and form positive ions. Metals show this property. Down a group, electropositivity increases because atomic size increases, making it easier for the nucleus to lose its outermost electron.

Common mistakes

  1. 1.Confusing electropositivity with electronegativity (the tendency to attract shared electrons).
  2. 2.Attributing the increase in atomic radius down a group to an increase in nuclear charge, whereas the increased nuclear charge actually pulls electrons closer; it is the addition of new shells that dominates and increases the size.

Analysis and explanation

Electropositivity is a fundamental characteristic of metals, which explains their high reactivity with oxygen, water, and acids as described in the NCERT text. Alkali metals (lithium, sodium, potassium) are highly electropositive, soft, and have low densities.


For the OR part, the trend in atomic radii of alkali metals is explained by periodic principles. As we go down Group 1 (Na→K→Rb→Cs\text{Na} \rightarrow \text{K} \rightarrow \text{Rb} \rightarrow \text{Cs}), the principal quantum number increases, meaning new shells are added. This increases the atomic radius from 86 pm86\text{ pm} (for Na\text{Na} ion/atom trend) up to 282 pm282\text{ pm} for Cs\text{Cs}.

Interesting facts

Alkali metals like sodium and potassium are so reactive due to their high electropositivity that they must be stored under kerosene oil to prevent them from reacting with moisture and oxygen in the air.

Question details

Q2 of 30 questions

Board
CBSE
Class
Class 10
Subject
Science
Year
2020
Section
Section A
Marks
1
Type
Very Short Answer
Chapter
Metals and Non-metals
Topic
Chemical Properties of Metals
Bloom's level
Understanding
Syllabus topic
Reactivity of metals, basic periodic trends, and alkali metals

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Frequently asked questions

How many marks does this question carry in CBSE Class 10 Science 2020?

This question carries 1 mark in the CBSE Class 10 Science 2020 examination.

Which chapter does this question come from in Science?

This question is from the chapter "Metals and Non-metals" in the CBSE Class 10 Science syllabus.

What topic does this question cover in Science?

This question covers the topic "Chemical Properties of Metals" from CBSE Class 10 Science.

What type of question is this in the CBSE Class 10 Science 2020 paper?

This is a Very Short Answer question from Section A in the CBSE Class 10 Science 2020 paper.