Q9
3 marksShort AnswerSection A

What happens when (write chemical equation in each case) (a) ethanol is burnt in air ? (b) ethanol is heated with excess conc. H2SO4H_2SO_4 at 443 K ? (c) a piece of sodium is dropped into ethanol ?

Carbon and its Compounds
Chemical Properties of Carbon Compounds
Official Answer

The chemical reactions and observations for each case are as follows:


(a) Ethanol is burnt in air:

Ethanol burns readily in the presence of oxygen (air) with a clear, blue flame to undergo complete combustion, producing carbon dioxide gas, water vapor, heat, and light.

Chemical Equation: C2H5OH+3O22CO2+3H2O+Heat and Light\text{Chemical Equation: } C_2H_5OH + 3O_2 \rightarrow 2CO_2 + 3H_2O + \text{Heat and Light}


(b) Ethanol is heated with excess conc. H2SO4H_2SO_4 at 443 K:

Heating ethanol at 443 K443\text{ K} with excess concentrated sulphuric acid results in the dehydration of ethanol to form ethene (an unsaturated hydrocarbon) and water. In this reaction, concentrated sulphuric acid acts as a dehydrating agent because it removes water from ethanol.

Chemical Equation: CH3CH2OHHot conc. H2SO4,443 KCH2=CH2+H2O\text{Chemical Equation: } CH_3-CH_2OH \xrightarrow{\text{Hot conc. } H_2SO_4, 443\text{ K}} CH_2=CH_2 + H_2O


(c) A piece of sodium is dropped into ethanol:

Ethanol reacts with sodium metal at room temperature to form sodium ethoxide with the rapid evolution of hydrogen gas (which can be tested with a burning splinter, producing a characteristic 'pop' sound).

Chemical Equation: 2CH3CH2OH+2Na2CH3CH2ONa+H2\text{Chemical Equation: } 2CH_3CH_2OH + 2Na \rightarrow 2CH_3CH_2ONa + H_2 \uparrow

CombustionCarbon dioxideDehydrationEtheneDehydrating agentSodium ethoxideHydrogen gas

Marking Scheme

  • 11 mark
  • 21 mark
  • 31 mark

Hint

Recall that combustion yields carbon dioxide and water; heating with concentrated acid at 443 K443\text{ K} removes water to form an alkene; and active metals like sodium displace hydrogen from the hydroxyl group.

Quick Oral Answer

When sodium is added to ethanol, hydrogen gas is evolved. We can confirm this by bringing a burning splinter near the mouth of the test tube; it will extinguish with a 'pop' sound.

Analysis & Explanation

These three reactions demonstrate key chemical properties of ethanol:

  1. Combustion: Like most organic compounds, ethanol is highly flammable and burns cleanly, making it a useful fuel additive.
  2. Dehydration: Concentrated H2SO4H_2SO_4 is a strong dehydrating agent. At high temperatures (443 K443\text{ K}), it removes an OH-OH group from one carbon and a hydrogen atom from the adjacent carbon of ethanol, establishing a carbon-carbon double bond (C=CC=C) to form ethene.
  3. Reaction with Active Metals: Alcohols are weakly acidic. Sodium displaces the hydrogen atom of the hydroxyl group (OH-OH) to release hydrogen gas and form an alkoxide salt (sodium ethoxide).

Common Mistakes

  1. 1Writing the product of dehydration as ethane instead of ethene.
  2. 2Forgetting to write the reaction conditions (such as 443 K443\text{ K} and conc. H2SO4H_2SO_4) over the arrow.
  3. 3Balancing errors in the combustion equation.

Interesting Facts

Ethanol is used as an additive in petrol (gasohol) because it is a cleaner-burning fuel that releases fewer greenhouse gases upon combustion.

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Frequently Asked Questions

How many marks does this question carry in CBSE Class 10 Science 2017?

This question carries 3 marks in the CBSE Class 10 Science 2017 examination.

Which chapter does this question come from in Science?

This question is from the chapter "Carbon and its Compounds" in the CBSE Class 10 Science syllabus.

What topic does this question cover in Science?

This question covers the topic "Chemical Properties of Carbon Compounds" from CBSE Class 10 Science.

What type of question is this in the CBSE Class 10 Science 2017 paper?

This is a Short Answer question from Section A in the CBSE Class 10 Science 2017 paper.