Question 103 marksShort AnswerSection A

Three elements ‘X’, ‘Y’ and ‘Z’ have atomic numbers 7, 8 and 9 respectively. (a) State their positions (Group number and period number both) in the Modern Periodic Table. (b) Arrange these elements in the decreasing order of their atomic radii. (c) Write the formula of the compound formed when ‘X’ combines with ‘Z’.

Metals and Non-metals
Periodic Trends and Chemical Formulas

Official answer

(a) Positions of 'X', 'Y' and 'Z' in the Modern Periodic Table:

  • 'X' (Atomic number 7): Electronic configuration is 2,52, 5. It has 22 shells and 55 valence electrons.
  • Period: 22
  • Group: 10+5=1510 + 5 = 15
  • 'Y' (Atomic number 8): Electronic configuration is 2,62, 6. It has 22 shells and 66 valence electrons.
  • Period: 22
  • Group: 10+6=1610 + 6 = 16
  • 'Z' (Atomic number 9): Electronic configuration is 2,72, 7. It has 22 shells and 77 valence electrons.
  • Period: 22
  • Group: 10+7=1710 + 7 = 17

(b) Decreasing order of atomic radii:

  • Order: X>Y>ZX > Y > Z
  • Reason: All three elements belong to the same period (Period 2). As we move from left to right across a period, the nuclear charge increases due to the addition of protons in the nucleus. This stronger nuclear charge pulls the valence electrons closer to the nucleus, thereby decreasing the atomic radius.

(c) Formula of the compound formed when 'X' combines with 'Z':

  • Element 'X' (Nitrogen) has 55 valence electrons, so its valency is 8−5=38 - 5 = 3.
  • Element 'Z' (Fluorine) has 77 valence electrons, so its valency is 8−7=18 - 7 = 1.
  • By crossing over their valencies:

Element XElement Z\text{Element } X \quad \text{Element } Z

Valency: 31\text{Valency: } 3 \quad\quad\quad\quad 1

  • Formula: XZ3XZ_3 (which represents Nitrogen trifluoride, NF3NF_3).
Answer keywords:Period 2Group 15Group 16Group 17nuclear chargeatomic radius decreasesX>Y>ZX > Y > ZXZ3XZ_3

Marking scheme

  1. 1.Correctly identifying the period (2) and group numbers (15, 16, 17) for all three elements. (1 mark)
  2. 2.Arranging the elements in the correct decreasing order of atomic radii (X>Y>ZX > Y > Z) with a valid scientific reason. (1 mark)
  3. 3.Deducing the correct valencies and writing the final molecular formula XZ3XZ_3. (1 mark)

Hint

Write down the electronic configurations of elements with atomic numbers 7, 8, and 9. Remember that atomic size decreases from left to right across a period.

Quick oral answer

Elements X, Y, and Z are Nitrogen, Oxygen, and Fluorine respectively. Nitrogen has a valency of 3 and Fluorine has a valency of 1, so they combine to form the covalent compound NF3NF_3 (represented as XZ3XZ_3).

Common mistakes

  1. 1.Writing group numbers as 5, 6, and 7 instead of 15, 16, and 17.
  2. 2.Reversing the atomic radii trend (writing Z>Y>XZ > Y > X under the assumption that more electrons mean a larger size).
  3. 3.Writing the compound formula incorrectly as ZX3ZX_3 or XZXZ.

Analysis and explanation

  1. Position Determination: The number of shells determines the period number, and the number of valence electrons determines the group number (for elements with ≥3\ge 3 valence electrons, Group = 10+valence electrons10 + \text{valence electrons}). Thus, X(7)X(7) is in Group 15, Y(8)Y(8) is in Group 16, and Z(9)Z(9) is in Group 17.
  2. Atomic Size Trend: Across Period 2, the atomic number increases from 7 to 9. The electrons are added to the same shell while the positive charge on the nucleus increases. This results in a stronger electrostatic pull on the outer electrons, making the atom smaller. Hence, X>Y>ZX > Y > Z.
  3. Chemical Formula: 'X' needs 3 electrons to complete its octet, while 'Z' needs 1 electron. Therefore, one atom of 'X' will share electrons with three atoms of 'Z' to form a stable covalent compound with the formula XZ3XZ_3.

Interesting facts

Element X is Nitrogen, which makes up 78% of our atmosphere; Element Y is Oxygen, essential for respiration; and Element Z is Fluorine, the most reactive non-metal known.

Question details

Q10 of 36 questions

Board
CBSE
Class
Class 10
Subject
Science
Year
2016
Section
Section A
Marks
3
Type
Short Answer
Chapter
Metals and Non-metals
Topic
Periodic Trends and Chemical Formulas
Bloom's level
Analyzing
Syllabus topic
Modern Periodic Table, periodic trends in atomic size, valency, and formula of compounds.

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Frequently asked questions

How many marks does this question carry in CBSE Class 10 Science 2016?

This question carries 3 marks in the CBSE Class 10 Science 2016 examination.

Which chapter does this question come from in Science?

This question is from the chapter "Metals and Non-metals" in the CBSE Class 10 Science syllabus.

What topic does this question cover in Science?

This question covers the topic "Periodic Trends and Chemical Formulas" from CBSE Class 10 Science.

What type of question is this in the CBSE Class 10 Science 2016 paper?

This is a Short Answer question from Section A in the CBSE Class 10 Science 2016 paper.